If you want AdGuard VPN and AdGuard Ad Blocker to work together, check if Compatibility mode is enabled in AdGuard VPN.
Go to Settings → App settings → Advanced settings → Operating mode. Select Compatibility mode with AdGuard.**
You need to enable Compatibility mode only in one of the AdGuard apps: the other app updates automatically.
In Android, you can't run multiple VPN services simultaneously. If you try running another VPN-based app together with AdGuard, it will cause serious problems.